Comprehensive comparison of pore-scale models for multiphase flow in porous media

A paper that I contributed simulations to was recently published in the journal PNAS. The contributors were asked to simulate the pore-scale oil/water displacement pattern in a radial Hele-Shaw cell with posts, under different injection rates and wettability conditions. Experimental data was provided and the idea was to compare the pros and cons of different modeling techniques. It was a challenging task.

I submitted phase-field results which were accurate for several of the cases, but like many techniques struggled with strong imbibition. I would like to point out one correction that never made it into the final paper. Fig. 4B shows my results, PF2, producing a very inaccurate finger width of Wf=93. This value was calculated from my original submission, which stopped well before the injected fluid reached the boundary. During revision I ran the simulation to completion (see results in supplementary information) which produced a finger width of Wf=20, close to the experimental value. Unfortunately I missed that Fig 4B was not updated with the correct Wf in the final revision, and the paper was published with the old value.

Judges sermon series

Several years ago Gordon Hugenberger gave an excellent series of sermons at Park Street Church on the book of Judges, which is one of the most violent, disturbing, and confusing books in the Bible. Since Judges is not a popular book for study guides, I found the sermon series to be a valuable reference for understanding the most difficult parts of the book. Gordon makes a convincing case that although the Israelites are in a downward spiral, the Judges actually build toward Samson, who is a prefigurement of Christ.

Unfortunately the sermons were given over several years and are difficult to find on the church website. Below I have collected the sermons and put them in scripture order along with a link to the audio with the hope of making this valuable material accessible to others. Enjoy.

Paper in Electrochemistry Communications

Comparison of (a) simulated and (b)-(c) observed lithiated diamond cores in LixFePO4 single particles.

My postdoc with Prof. Martin Bazant officially ended 6 years ago, but it’s still generating research papers! A paper that we wrote was just published at Electrochemistry Communications, and is available for free at this link until October 28.

Over that time we had been following the progress in advanced microscopy techniques applied to battery materials, and realized that our model of lithium iron phosphate captured many of the features researchers were imaging. The model helped resolve conflicting reports from different researchers who looked at a variety of different size LiFePO4 crystals. The smallest crystals at the nanoscale are controlled by their surface properties, while micron sized crystals are dominated by elastic energy. Just by running larger simulations we observed the transition that experimentalists were imaging. After a bunch of time invested on nights and weekends, this paper is finally finished.